In situ FTIR and TPD studies on the interaction of NOx with CeO2
نویسندگان
چکیده
Introduction Current and upcoming environmental policy in the developed countries is imposing significant decreases in NOX emissions from combustion processes such as vehicle engines. Traditional three-way catalysts are ineffective under O2 rich atmosphere lean-burn engines operate under. Lean NOx trap (LNT) technology developed for treating lean automotive exhaust emission is considered one of the most promising NOx reduction technologies.
منابع مشابه
Characterization of SO2-Poisoned Ceria-Zirconia Mixed Oxides
CeO2, ZrO2, and a series of CexZr1-xO2 catalysts with 1 wt% Pd were exposed to fixed exposures of SO2 under oxidizing environments and then characterized by FTIR, pulse-reactor studies with CO and O2, and temperature-programmed desorption (TPD). For exposures above 473 K, sulfates were formed on all of the materials; however, the results are consistent with the formation of bulk sulfates on CeO...
متن کاملAdsorption of CO and NO on Ceria- and Pt-Supported TiO2: In Situ FTIR Study
Pt/TiO2, Ce/TiO2 and binary system PtCe/TiO2 catalysts were prepared by impregnation method and the structural properties of these catalysts were investigated by means of XRD, CO-TPD and UV-vis diffuse reflectance spectroscopy. As investigated by XRD, the composition of the prepared samples anatase and rutile phases with higher amount of anatase phase and its particle size was in the range of 1...
متن کاملEx-situ studies on calcinations of structural, optical and morphological properties of post-growth nanoparticles CeO2 by HRTEM and SAED
Nanocrystalline particles of Cerium Oxide (CeO2) have been prepared by the chemical precipitation method using Cerium nitrate and Urea with a molar ratio of 1:2. The results revealed that the formation of CeO2 fine particles is influenced by molar ratio of metal nitrates to fuel. Well faceted CeO2 nanoparticles, were synthesized by thermal-assisted dissociation ...
متن کاملEx-situ studies on calcinations of structural, optical and morphological properties of post-growth nanoparticles CeO2 by HRTEM and SAED
Nanocrystalline particles of Cerium Oxide (CeO2) have been prepared by the chemical precipitation method using Cerium nitrate and Urea with a molar ratio of 1:2. The results revealed that the formation of CeO2 fine particles is influenced by molar ratio of metal nitrates to fuel. Well faceted CeO2 nanoparticles, were synthesized by thermal-assisted dissociation ...
متن کاملSynthesis of nano-sized ceria (CeO2) particles via a cerium hydroxy carbonate precursor and the effect of reaction temperature on particle morphology
Cerium oxide (CeO2) or ceria has been shown to be an interesting support material for noble metals in catalysts designed for emission control, mainly due to its oxygen storage capacity. Ceria nanoparticles were prepared by precipitation method. The precursor materials used in this research were cerium nitrate hexahydrate (as a basic material), potassium carbonate and potassium hydroxide (as pre...
متن کامل